Good non-conventional shoujo: After School Nightmare (although it's probably the MOST nonconventional shoujo I've ever read and it will fuck with your brain. Majorly.) The main female character (well, both of them) can be kind of annoying and selfish, but they both grow out of it eventually. ANYWAY. I CAN'T RECOMMEND THIS HIGHLY ENOUGH.
... aaaaaand I've heard that Skip Beat is good but I'm too lazy to catch up on it. /shot